Product ID:FREON 12 FLUOROCARBON
MSDS Date:12/17/1990
FSC:6830
NIIN:00-531-8102
MSDS Number: BNPQB

DUPONT

CHESTNUT RUN PLAZA 711S
WILMINGTON, DE 19890-0711
US

Emergency Phone: 800-423-9300(CHEMTREC)/800-441-3637

Info Phone: 800-441-9450

Preparer: DR W BROCK

Cage: EO596

DUPONT

WILMINGTON, DE 19898-5000 US

Telephone: 8004413637

Cage: EO596

METHANE, DICHLORODIFLUORO ("FREON" 12 FLUOROCARBON) (SARA

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: 100%

OSHA PEL 1000 PPM 8 HR TWA

ACGIH TLV: 1000 PPM 8 HR TWA

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:INHAL 4-HR LC50: 80,000 PPM (RAT) **
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT WITH VAPOR MAY CAUSE EYE
IRRITATION. SKIN CONTACT WITH LIQUID MAY CAUSE FROSTBITE.
INHALATION OF VAPORS MAY CAUSE TEMPORARY NERVOUS SYSTEM DEPRESSION
W/ANETHETIC EFFECTS. TEMPORARY ALTERAT ION OF THE HEART'S
ELECTRICAL ACTIVITY.
** ORAL ALD: >1000 MG/KG (RATS).
Explanation of Carcinogenicity:NONE OF THE COMPONENTS IN THIS MAT'L IS
LISTED BY IARC, NTP, OSHA, OR ACGIH AS A CARCINOGEN.
Effects of Overexposure:EYE: DISCOMFORT, TEARING, BLURRING OF VISION.
INHALATION: NERVOUS SYSTEM DEPRESSION: DIZZINESS, HEADACHE,
CONFUSION, INCOORDINATION AND LOSS OF CONSCIOUSNESS. IRREGULAR
PULSE, PALPITATIONS, INADEQUAT E CIRCULATION, OR THE EFFECTS OF
EXCLUSION OF OXYGEN W/GROSSLY EXCESSIVE EXPOSURES.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
DISEASES OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE
INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.

First Aid:INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. KEEP PERSONS
CALM. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING
IS DIFFICULT, GIVE OXYGEN. CALL DR. SKIN: FLUSH W/WATER. TREAT FOR
FROSTBITE IF NECESSARY BY GENTLY WARMING AFFECTED AREA. EYE: IMMED
FLUSH W/PLENTY OF WATER 15 MIN. CALL DR. NOTES TO PHYSICIAN:
BECAUSE OF A POSSIBLE DISTURBANCE OF CARDIAC RHYTHM, CATECHOLAMINE
DRUGS, SUCH***

Flash Point:WILL NOT BURN
Extinguishing Media:AS FOR COMBUSTIBLES IN AREA.
Fire Fighting Procedures:SCBA IS REQUIRED IF CYLINDERS RUPTURE OR
CONTENTS ARE RELEASED UNDER FIRE CONDITIONS.
Unusual Fire/Explosion Hazard:USE WATER SPRAY OR FOG TO COOL
CONTAINERS. CYLNDRS EQUIPPED W/PRESSURE & TEMP RELIEF DEVICES BUT
MAY RUPTURE UNDER FIRE CONDITIONS. DECOMPOSITION MAY OCCUR.

Spill Release Procedures:NOTE: REVIEW FIRE & EXPLOSION HAZARDS & SAFETY
PRECAUTIONS BEFORE PROCEEDING W/CLEAN UP. USE PERSONAL PROTECTIVE
EQUIPMENT DURING CLEAN UP. VENT AREA-ESPECIALLY LOW PLACES WHERE
HEAVY VAPORS MIGHT COL LECT. REMOVE OPEN FLAMES. FOR LRG SPILLUSE
SCBA.

Handling and Storage Precautions:STORE IN CLEAN, DRY AREA. DO NOT HEAT
ABOVE 125F. USE WITH SUFFICIENT VENTILATION TO KEEP EMPLOYEE
EXPOSURE BELOW RECOMMENDED LIMITS.
Other Precautions:N/K
*** AS
EPINEPHRINE, SHOULD BE USED WITH SPECIAL CAUTION IN SITUATIONS OF
EMERGENCY LIFE SUPP ORT.

Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS, NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
SELF-CONTAINED BREATHING APPARATUS (SCBA) IS REQUIRED IF A LARGE
RELEASE OCCURS.
Ventilation:NORMAL VENT FOR STD MFR PROCEDURES IS GEN ADEQUATE. LOCAL
EXHAUST WHEN LRG AMTS ARE RELEASED. MECHAN VENT IN LOW PLACES.
Protective Gloves:LINED BUTYL GLOVES.
Eye Protection:CHEM SPLASH GOGGLES WHEN HANDLING LIQUID
Supplemental Safety and Health

HCC:G3
Boiling Pt:B.P. Text:-22F,-30C
Decomp Temp:Decomp Text:>1400F,>760
Vapor Pres:94.5 PSIA*
Vapor Density:4.26 @ 25C
Spec Gravity:1.315 G/CC @25C
pH:NEUTRL
Evaporation Rate & Reference:N/K * 25 C
Solubility in Water:0.028WT% @1 ATM @25C
Appearance and Odor:COLORLESS, CLEAR LIQUEFIED GAS, SLIGHT ETHEREAL
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS-POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:BY HIGH TEMPS FORMING: HYDROCHLORIC &
HYDROFLUORIC ACIDS-POSSIBLY CARBONYL HALIDES.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS. RECLAIM BY DISTILLATION OR REMOVE TO PERMITTED WASTE
FACILITY. REPORTABLE QUANTITY: 5000 LBS/2250 KG.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.